Physico-chemical modelling of the sorption reactivity of true trace colloids

Citation
Ev. Polyakov et al., Physico-chemical modelling of the sorption reactivity of true trace colloids, CZEC J PHYS, 49, 1999, pp. 773-781
Citations number
9
Categorie Soggetti
Physics
Journal title
CZECHOSLOVAK JOURNAL OF PHYSICS
ISSN journal
00114626 → ACNP
Volume
49
Year of publication
1999
Part
2
Supplement
1
Pages
773 - 781
Database
ISI
SICI code
0011-4626(1999)49:<773:PMOTSR>2.0.ZU;2-5
Abstract
Physico-chemical model of trace hydrolyzed element adsorption by II-form of ion-exchange resin is considered. The model implies the existence of both ionic forms and trace hydroxide colloids in aqueous phase and predicts two sharp maxima separated by a plateau on the adsorption diagram. It is shown that complicated adsorption profile arises as a result of superposition of the trace hydroxide colloid formation/dissolution by-processes accompanied by irreversible ageing of the colloid.