Determination of tracer diffusion coefficients of (NaCl)-Na-22 as functionof magnesium chloride concentration in water at 25 degrees C

Citation
J. Ahl et S. Liukkonen, Determination of tracer diffusion coefficients of (NaCl)-Na-22 as functionof magnesium chloride concentration in water at 25 degrees C, CZEC J PHYS, 49, 1999, pp. 867-872
Citations number
11
Categorie Soggetti
Physics
Journal title
CZECHOSLOVAK JOURNAL OF PHYSICS
ISSN journal
00114626 → ACNP
Volume
49
Year of publication
1999
Part
2
Supplement
1
Pages
867 - 872
Database
ISI
SICI code
0011-4626(1999)49:<867:DOTDCO>2.0.ZU;2-3
Abstract
The tracer diffusion coefficients of sodium-aa-chloride were determined as function of magnesium chloride concentrations in aqueous solutions(10(-4).. . 1 mol dm(-3)) at 25 degrees C. Closed capillary method was used in experi ments. The most accurate method to calculate the tracer diffusion coefficie nt from an infinite series solution was further developed. The Onsager limi ting law was verified to the tracer diffusion of (NaCl)-Na-22 in aqueous ma gnesium chloride in low concentration region.