Gamma ray and accelerated electron beam application in the chemistry of pol
yelectrolytes is presented. The polyelectrolytes preparation is based on ra
diation induced polymerization of aqueous solutions containing an appropria
te mixture of monomers such as acrylamide, acrylic acid, vinyl acetate, dia
llyldimethylammonium-chloride and certain initiators, complexing agents and
chain transfer agents. The effects of absorbed dose, rate of absorbed dose
and chemical composition of aqueous solution on the polymerization process
are discussed. The results obtained by testing these polyelectrolytes with
waste water from food industry are also given.