At low pressure, chemical vapor deposition (CVD) diamond growth by conventi
onal techniques such as micro-wave plasma and hot-filament have been achiev
ed by metastable precursor species. Moreover, bulk diamond at extremely hig
h pressures and temperatures was consistently originated by the nature of d
iamond-graphite phase transition. CVD diamond growth has four problems with
these conventional techniques. Excluding contaminated air from low pressur
e reactive systems has been problematic. It is very difficult to control th
e concentration of atomic hydrogen at high pressures. The growth rate is un
satisfactory and the running cost of gases are high.
However, the hot-filament CVD technique at atmospheric pressure overcomes t
hese problems. We have found that in order to control the concentration of
atomic hydrogen, the residence time of the input gas and the methane-hydrog
en concentration ratio needed to be varied at each pressure. The relationsh
ip between the quality of deposited diamond and the pressure have been also
investigated by Raman spectroscopy and X-ray diffraction patterns (XRD).
The growth rate at atmospheric pressure (1060.1000 Pa) was found to be grea
ter than that at the conventional pressure (5000 Pa). At atmospheric pressu
re, the growth rate abruptly increases with the residence time. XRD analysi
s revealed that the quality of diamonds grown at atmospheric pressure was h
igher than that of diamonds produced at low pressures. Furthermore, high qu
ality diamond growth was achieved with a long residence time of the input g
as at atmospheric pressure. (C) 1999 Published by Elsevier Science S.A. All
rights reserved.