P. Bosch et al., PHOTOPOLYMERIZATION OF HYDROXYETHYLMETHACRYLATE IN THE FORMATION OF ORGANIC-INORGANIC HYBRID SOL-GEL MATRICES, Journal of polymer science. Part A, Polymer chemistry, 34(16), 1996, pp. 3289-3296
Hydroxyethylmethacrylate (HEMA) monomer in different contents was used
in the preparation of transparent organic-inorganic hybrid sol-gel ma
trices. The matrices were studied by analytical techniques before and
after irradiation. An increase in the homogeneity of the composite mat
erial after the irradiation of HEMA, and a chemical linkage of the mon
omer with the surface has been observed. Photopolymerization processes
were studied by differential scanning calorimetry (DSC). Details of t
he irradiation times, polymerization rates, and DSC related parameters
of HEMA in the sol-gel matrices are reported. (C) 1996 John Wiley & S
ons, Inc.