Photodegradation of free and complex cyanides in irradiated homogeneous and heterogeneous systems

Citation
V. Augugliaro et al., Photodegradation of free and complex cyanides in irradiated homogeneous and heterogeneous systems, FR ENV BULL, 8(5-6), 1999, pp. 350-357
Citations number
4
Categorie Soggetti
Environment/Ecology
Journal title
FRESENIUS ENVIRONMENTAL BULLETIN
ISSN journal
10184619 → ACNP
Volume
8
Issue
5-6
Year of publication
1999
Pages
350 - 357
Database
ISI
SICI code
1018-4619(199905/06)8:5-6<350:POFACC>2.0.ZU;2-#
Abstract
The photodegradation of free and complex cyanides in aqueous medium in homo geneous and heterogeneous systems irradiated by UV and near-UV light has be en investigated. Polycrystalline TiO2 was used as photocatalyst. The kineti cs of free cyanide photo-oxidation in heterogeneous systems is well describ ed by the Langmuir-Hinshelwood model. The degradation of Fe(III) complex cy anides in aqueous medium under UV or near-UV radiation is also kinetically modelled Key words: photocatalysis, free cyanides photo-oxidation, complex cyanides photodegradation, TiO2 photocatalyst.