Ozone destruction on ice

Citation
S. Langenberg et U. Schurath, Ozone destruction on ice, GEOPHYS R L, 26(12), 1999, pp. 1695-1698
Citations number
12
Categorie Soggetti
Earth Sciences
Journal title
GEOPHYSICAL RESEARCH LETTERS
ISSN journal
00948276 → ACNP
Volume
26
Issue
12
Year of publication
1999
Pages
1695 - 1698
Database
ISI
SICI code
0094-8276(19990615)26:12<1695:ODOI>2.0.ZU;2-N
Abstract
The destruction of ozone on ice surfaces was studied with;tn ice-coated fus ed silica column used as a very long flow tube. Ozone destruction was found to be very slow. At :223 K and 258 K the measured reaction probabilities f all in the range 2 x 10(-8) - 4 x 10(-10), decreasing with increasing ozone concentration (20 - 1000 nbar). The observed kinetics are explained by an at least two step mechanism. The bn reaction rates observed are insignifica nt for ozone destruction in cirrus clouds.