Synthesis, characterization and aqueous-biphase catalysis of the rutheniumdimer Na[{O3S(C6H4)CH2C(CH2PPh2)(3)Ru}(2)(mu-Cl)(3)]

Authors
Rojas, I Linares, FL Valencia, N Bianchini, C
Citation
I. Rojas et al., Synthesis, characterization and aqueous-biphase catalysis of the rutheniumdimer Na[{O3S(C6H4)CH2C(CH2PPh2)(3)Ru}(2)(mu-Cl)(3)], J MOL CAT A, 144(1), 1999, pp. 1-6
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
144
Issue
1
Year of publication
1999
Pages
1 - 6
Database
ISI
SICI code
1381-1169(19990722)144:1<1:SCAACO>2.0.ZU;2-P
Abstract
The dimer Na[{O3S(C6H4)CH2C(CH2PPh2)(3)Ru}(2)(mu-Cl)(3)] . 3H(2)O has been synthesized by the reaction of the tripodal Ligand NaO3S(C6H4)CH2C(CH2PPh2) (3) with the ruthenium complex [RuCl2(DMSO)(4)]. The dimeric complex is an effective catalyst precursor for the liquid-biphase hydrogenation of the do uble bond in various alkenes (l-hexene, 1-decene, allylbenzene, styrene) as well as the heteroaromatic ring in benzo[b]thiophene and quinoline. All th e metal remains in the polar phase at the end of the catalytic reactions. ( C) 1999 Elsevier Science B.V. All rights reserved.