Reductive carbonylation of 2,4-dinitrotoluene to 2,4-toluendiurethane withpalladium(1,10-phenanthroline)(2) (hexafluorophosphate)(2), as catalyst, and 1,10-phenanthrolinium hexafluorophosphate, as cocatalyst.

Authors
Santi, R Romano, AM Panella, F Mestroni, G Sessanti, A Santi, O
Citation
R. Santi et al., Reductive carbonylation of 2,4-dinitrotoluene to 2,4-toluendiurethane withpalladium(1,10-phenanthroline)(2) (hexafluorophosphate)(2), as catalyst, and 1,10-phenanthrolinium hexafluorophosphate, as cocatalyst., J MOL CAT A, 144(1), 1999, pp. 41-45
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
144
Issue
1
Year of publication
1999
Pages
41 - 45
Database
ISI
SICI code
1381-1169(19990722)144:1<41:RCO2T2>2.0.ZU;2-C
Abstract
Reductive carbonylation of 2,4-dinitrotoluene (DNT) affords 2,4-toluendiure thane (TDU) with unprecedented high yield and selectivity when palladium(1, 10-phenanthroline)(2)(hexafluorophosphate)(2) [Pd(phen)(2)(PF6)(2)] is used as catalyst, in combination with free 1,10-phenanthroline (phen) and 1,10- phenanthrolinium hexafluorophosphate (phenHFP(6)), as acid cocatalyst. (C) 1999 Elsevier Science B.V. All rights reserved.