Some applications-of vibrational spectroscopy in conformational analysis

Authors
Fishman, AI Remizov, AB Stolov, AA
Citation
Ai. Fishman et al., Some applications-of vibrational spectroscopy in conformational analysis, J MOL STRUC, 481, 1999, pp. 303-306
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
481
Year of publication
1999
Pages
303 - 306
Database
ISI
SICI code
0022-2860(19990504)481:<303:SAVSIC>2.0.ZU;2-9
Abstract
We report some vibrational spectroscopic approaches to studying conformatio nal equilibria and kinetics, which were developed in recent years: (i) inve stigation of relative band dichroism in polarized IR spectra of crystals; ( ii) kinetic investigations of conformational transitions in liquid solution s; and (iii) use: of conformationally inhomogeneous compounds as probes for studying molecular mobility and free volume distribution in polymers. (C) 1999 Elsevier Science B.V. All rights reserved.