Recovery of actinides extracted by Truer solvent from high level waste using complexing agents II. Counter-current studies

Citation
Rr. Chitnis et al., Recovery of actinides extracted by Truer solvent from high level waste using complexing agents II. Counter-current studies, J RAD NUCL, 240(3), 1999, pp. 727-730
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN journal
02365731 → ACNP
Volume
240
Issue
3
Year of publication
1999
Pages
727 - 730
Database
ISI
SICI code
0236-5731(199906)240:3<727:ROAEBT>2.0.ZU;2-B
Abstract
These studies are an extension of earlier work on the recovery of actinides extracted by Truex solvent from simulated high level waste solution, with a mixture of weak acid, weak base and complexing agent used as a strippant. The effectiveness of the proposed strippant, consisting of formic acid, hy drazine hydrate and citric acid, is tested in a counter-current mode using mixer-settler in the present studies. The studies show that near quantitati ve recovery of americium and plutonium is feasible from acid-bearing Truer solvent with no reflux (reextraction) of activity. Use of this strippant re duces considerably the generation of secondary waste.