Sn. Kundu et al., Photoluminescence studies in CuInxGa1-xSe2 films prepared by graphite box annealing of In/Ga/Cu/Se stacked elemental layers, MOD PHY L B, 13(5), 1999, pp. 153-158
CuInxGa1-xSe2 films were synthesized by graphite box annealing of In/Ga/Cu/
Se stacked elemental layers deposited by thermal evaporation onto sodalime
glass substrates. Photoluminescence (PL) studies were carried out in near s
toichiometric and copper-rich films with Ga/(In+Ga) ratios varying between
0.24-0.29. The PL spectra were dominated by peaks at similar to 1.19 eV and
0.87 eV with a shoulder at similar to 0.84 eV. There was also a peak aroun
d 1.3 eV which could be assigned to the absorption from the split-off band.
The transitions at similar to 1.19 eV and 0.87 eV were due to excitonic tr
ansition and donor-acceptor pair formation respectively.