R. Mews et al., 3-COORDINATE SULPHUR(VI)-NITROGEN SPECIES - AN ATTEMPT TO BREATHE SOME NEW LIFE INTO AN OLD TOPIC, Coordination chemistry reviews, 158, 1997, pp. 233-273
The review describes the syntheses, structures and reaction chemistry
of three-coordinate nitrogen-containing sulphur(VI) compounds includin
g the sulphur triimides [(RN)(3)S], sulphonyl diimides [(RN)(2)SO], su
lphonyl imides [RNSO2] and sulphene imides [R2CS(O)NR]. Comparisons ar
e made with phosphorus(V) analogues. (C) 1997 Elsevier Science S.A.