Synthesis and properties of the phthalocyanines containing eugenol (4-allyl-2-methoxyphenol)

Citation
E. Agar et al., Synthesis and properties of the phthalocyanines containing eugenol (4-allyl-2-methoxyphenol), TURK J CHEM, 23(2), 1999, pp. 131-137
Citations number
29
Categorie Soggetti
Chemistry
Journal title
TURKISH JOURNAL OF CHEMISTRY
ISSN journal
13000527 → ACNP
Volume
23
Issue
2
Year of publication
1999
Pages
131 - 137
Database
ISI
SICI code
1300-0527(1999)23:2<131:SAPOTP>2.0.ZU;2-H
Abstract
New metal-free and metallophthalocyanines (M=Cu(II), Ni(II), Co(II), Zn(II) and Fe(II)) substituted with eugenol (4-allyl-2-methoxyphenol) from 1,2-di cyano-4-nitrobenzen are described. Cyclotetramerization of the substituted phthalonitrile leads to a product very soluble in common organic solvents. The characterization of the compounds was accomplished by elemental analysi s, H-1 NMR, C-13 NMR, IR and UV-VIS spectral data.