Indium surface segregation during the growth of Ga1-xInxAs by chemical beam
epitaxy is evidenced in real time by reflection high-energy electron diffr
action. An efficient way to suppress the compositional broadening of GaAs o
n the GaInAs interface resulting from the In segregation effect is proposed
. It consists in using the chemical reaction of AsCl3 molecules at the surf
ace, which is shown to etch layer by layer the Ga1-xInxAs alloy. Monolayer
etching precision is thus obtained and used to eliminate the In accumulatio
n at the GaInAs surface and the related interface broadening. (C) 1999 Amer
ican Institute of Physics. [S0003-6951(99)03526-3].