Contribution of the isotropic phase to the rheology of partially anisotropic coal-tar pitches

A commercial impregnating coal-tar pitch was thermally treated at 430 degre es C for 2-5 h in nitrogen. Resultant pitches, which contained mesophase ra nging from 10 to 46 vol.%, were filtered to separate the isotropic phases, in order to study their contribution to the rheology of the whole pitches. The parent pitch, thermally treated pitches and the individual isotropic ph ases were characterized by measuring their elemental composition, softening point, carbon yield, solubility in toluene and in N-methyl-2-pyrrolidone, mesophase content (by optical microscopy) and X-ray diffraction parameters. The rheological behavior of the pitches and the isotropic phases was studi ed using steady shear rheometry. Results showed that not only had the whole pitches, which were partially anisotropic, a non-Newtonian behavior, but a lso the single isotropic phases. (C) 1999 Elsevier Science Ltd. All rights reserved.