The first organoelement oxides containing three different metals; synthesis and structure of (Ph2SiOR2SnOMO) [R = (CH2)(3)NMe2; M = (Bu2Sn)-Sn-t, (Bu2Ge)-Ge-t, PhB]

Authors
Beckmann, J Jurkschat, K Pieper, N Schurmann, M
Citation
J. Beckmann et al., The first organoelement oxides containing three different metals; synthesis and structure of (Ph2SiOR2SnOMO) [R = (CH2)(3)NMe2; M = (Bu2Sn)-Sn-t, (Bu2Ge)-Ge-t, PhB], CHEM COMMUN, (12), 1999, pp. 1095-1096
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
12
Year of publication
1999
Pages
1095 - 1096
Database
ISI
SICI code
1359-7345(19990621):12<1095:TFOOCT>2.0.ZU;2-Q
Abstract
Umpolung of ring strain by intramolecular Sn-N Lewis acid-Lewis base intera ction is the key for the synthesis of the first organoelement oxides of the type (Ph2SiOR2SnOMO) [R = (CH2)(3)NMe2; M = (Bu2Sn)-Sn-t, (Bu2Ge)-Ge-t, Ph B] which hold potential as precursors to tertiary metal oxides.