Synthesis of an amphiphilic bifunctional initiator with an aromatic group

Authors
Zhou, GC Huang, PC Zhu, HS
Citation
Gc. Zhou et al., Synthesis of an amphiphilic bifunctional initiator with an aromatic group, CHEM J CH U, 20(6), 1999, pp. 993-995
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
20
Issue
6
Year of publication
1999
Pages
993 - 995
Database
ISI
SICI code
0251-0790(199906)20:6<993:SOAABI>2.0.ZU;2-C
Abstract
An amphiphilic bifunctional initiator with an aromatic group, which is used in free radical interfacial copolymerization, p-toluoyl(3-carboxypropionyl )sebacoyl diperoxide(MBSD), was synthesized by the successive condensation of sebacoyl chloride with p-methylperoxybenzoic acid and monoperoxysuccinic acid under the catalysis of pyridine and further characterized by IR, H-1 NMR, MS, elemental analysis and the analysis of peroxide oxygen content.