Citation
Fp. Zheng et al., The preparation and characterization of nanosized Pd(OH)(2) and its application in the catalytic hydrogenolysis of HBIW, CHEM J CH U, 20(6), 1999, pp. 843-845
Citations number
7
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790
→ ACNP
Volume
20
Issue
6
Year of publication
1999
Pages
843 - 845
Database
ISI
SICI code
0251-0790(199906)20:6<843:TPACON>2.0.ZU;2-R
Abstract
Nanoscale Pd(OH)(2) was prepared by azeotropic distillation process for the
first time, and its structure was characterized by high resolution TEM, DL
S and UV-Vis absorption spectrum. The results show that the particle size o
f the prepared Pd(OH)(2) is of 37.3 nm and the particles are face-centred c
ubic polycrystalline, The prepared Pd(OH)(2) nanosized particles show a hig
her catalytic activity than 20% Pd(OH)(2)/C in the catalytic hydrogenolysis
of 2,4,6,8,10, 12-hexabenzyl-2,4,6,8,10,12-hexaazaisowurtztane (HBIW),