Efficient photooxygenation of olefins by a C-60 derivative bearing an organofluorine tail

Authors
Nagashima, H Hosoda, K Abe, T Iwamatsu, S Sonoda, T
Citation
H. Nagashima et al., Efficient photooxygenation of olefins by a C-60 derivative bearing an organofluorine tail, CHEM LETT, (6), 1999, pp. 469-470
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
6
Year of publication
1999
Pages
469 - 470
Database
ISI
SICI code
0366-7022(199906):6<469:EPOOBA>2.0.ZU;2-S
Abstract
A C-60 derivative bearing an organofluorine tail through the dimethylsilyl moiety (1) was proved to be an efficient photosensitizer in C6F6. Photooxyg enation of olefins or dienes was accomplished by catalysis of 1 (0.5 - 1.5 mol%) at room temperature under an oxygen atmosphere.