Dp. Arnold et Jz. Jiang, Mixed phthalocyaninato-porphyrinato europium(III) triple-decker sandwich complexes containing a conjugated dimeric porphyrin ligand, CHEM LETT, (6), 1999, pp. 483-484
The first examples of triple-decker europium(III) sandwich complexes contai
ning bis(octaethylporphyrinyl)butadiyne and phthalocyanine have been prepar
ed by condensation of NiOEP-C-4-OEPH2 (H(2)1.) and Li2Pc with Eu(acac)(3).
H2O. The complexes (Pc)Eu(1)Eu(Pc) and (1)Eu(Pc)Eu(Pc) were characterized b
y NMR, IR, Raman, UV-vis, and mass spectra.