Synthesis and characterization of a novel linear conjugated polymer, poly(2,5-didodecyloxy-1,4-phenyleneoctatetraynylene)

Authors
Kijima, M Kinoshita, I Shirakawa, H
Citation
M. Kijima et al., Synthesis and characterization of a novel linear conjugated polymer, poly(2,5-didodecyloxy-1,4-phenyleneoctatetraynylene), CHEM LETT, (6), 1999, pp. 531-532
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
6
Year of publication
1999
Pages
531 - 532
Database
ISI
SICI code
0366-7022(199906):6<531:SACOAN>2.0.ZU;2-C
Abstract
A novel linear conjugated polymer, poly(2,5-didodecyloxyphenyleneoctatetray nylene), was synthesized by an oxidative coupling of 2,5-didodecyloxy-1,4-d ibutadiynylbenzene in presence of a CuCl-TMEDA catalyst under O-2. The poly mer was stable under air and soluble in organic solvents. The structural an alyses and the characterizations were carried out by Raman, NMR, and UV-Vis .