Synthesis of polyisoprene having terminal vinyl group and copolymerizationof the macromonomer with ethylene and propylene

Authors
Endo, K Senoo, K Takakura, Y
Citation
K. Endo et al., Synthesis of polyisoprene having terminal vinyl group and copolymerizationof the macromonomer with ethylene and propylene, EUR POLYM J, 35(8), 1999, pp. 1413-1417
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN POLYMER JOURNAL
ISSN journal
00143057 → ACNP
Volume
35
Issue
8
Year of publication
1999
Pages
1413 - 1417
Database
ISI
SICI code
0014-3057(199908)35:8<1413:SOPHTV>2.0.ZU;2-P
Abstract
Synthesis of polyisoprene macromonomer having terminal vinyl group and graf t copolymerization of the macromonomer with ethylene and propylene was inve stigated. The polyisoprene macromonomer having terminal vinyl group (VIPM) was synthesized by a reaction of allyl chloride with living polyisoprene (P IP) initiated with s-butyllithium (s-BuLi) catalyst. The graft copolymers c onsisting of olefins and VIPM as a grafts was synthesized with classical Zi egler-Natta catalyst from the copolymerizations of the prepared VIPM with e thylene (E) and/or propylene (P). (C) 1999 Elsevier Science Ltd. All rights reserved.