We have measured the Doppler broadening of neutron time-of-flight spectra f
rom the reaction pi(-) p --> pi(0) + n in atomic states. From the data, we
infer that the kinetic energy distribution of pi(-)p-atoms in liquid and ga
seous hydrogen contains discrete 'high-energy' components with energies as
high as 200 eV attributed to Coulomb de-excitation. In liquid hydrogen, evi
dence for Coulomb de-excitation transitions with Delta n = 2 has been found
.