Reactions of nitridorhenium(V) and -osmium(VI) complexes with acylating agents

Interaction of Re(N)L-2 [L = N(PSPh2)(2)] 1 with (CF3CO)(2)O or RCOCl affor ded air-sensitive acylimido-Re(V) complexes trans-Re[NC(O)CF3](OCOCF3)L-2 2 or trans-Re[NC(O)R]ClL2 (R = CCl2H 3,CClH2 4, CH3 5), respectively. Treatm ent of 1 with (CX3CO)(2)O followed by recrystallization from CH2Cl2/hexane in air led to the formation of the corresponding parent imido complexes tra ns-Re(NH)(OCOCX3)L-2 (X = F 6, Cl 7). The structure of 7 has been character ized by X-ray crystallography. The Re-N, average Re-S, and Re-O distances a re 1.664(3), 2.441, and 2.116(3) Angstrom, respectively. Deprotonation of 6 or 7 with Et3N gave 1. Recrystallization of 3 from CH2Cl2/hexane in air re sulted in oxo-imido exchange and the isolation of the oxo-Re(V) species tra ns-Re(O)ClL2. Treatment of 1 with tosyl anhydride gave trans-Re(NH)(OTs)L-2 (OTs = tosyl) 8. Reaction of [n-Bu4N][OsNCl4] with KL afforded trans-Os(N) ClL2 9, which has been characterized by X-ray crystallography. The Os-N, Os -Cl, and average Os-S bond distances in 9 are 1.64(1), 2.577(4), and 2.429 Angstrom, respectively. Treatment of 10 with (CF3CO)(2)O, Ag(CF3CO2), or CF 3CO2H resulted in chloride substitution and the formation of trans-Os(N)(OC OCF3)L-2 10. The Os-N, Os-O, and average Os-S distances in 10 are 1.643(5), 2.271(4), and 2.419 Angstrom respectively. Treatment of 1 with [Ph3C]BF4 r esulted in the isolation of trans-Re(NCPh3)(F)L-2 11, presumably via the ca tionic tritylimido intermediate [Re(NCPh3)L-2](+). Reaction of 9 with [Ph3C ]BF4 led to chloride abstraction and the formation of five-coordinate [Os(N )L-2]BF4 12. The Os-Nand average Os-S distances in 12 are 1.646(5), and 2.3 64 Angstrom, respectively.