4-aminoantipyrine (AAP) was tested as a corrosion inhibitor for mild steel
in 2 M HCl solution using different techniques: weight loss, potentiodynami
c polarization and electrochemical impedance spectroscopy (EIS). The result
s showed that AAP is an inhibitor for mild steel in this medium. The inhibi
tion was assumed to occur via adsorption of the inhibitor molecule on the m
etal surface. In the 20 to 60 degrees C temperature range, the AAP adsorpti
on follows the Flory-Huggins isotherm and/or the El-Awady et al. kinetic-th
ermodynamic model. The protection efficiency increases with increasing inhi
bitor concentration (in the range 10(-3)-10(-2) M) but decreases with incre
asing temperature. The thermodynamic functions of dissolution and adsorptio
n processes were calculated.