THEORETICAL-MODEL FOR THE ANODIC-OXIDATION OF ORGANICS ON METAL-OXIDEELECTRODES

Authors
SIMOND O SCHALLER V COMNINELLIS C
Citation
O. Simond et al., THEORETICAL-MODEL FOR THE ANODIC-OXIDATION OF ORGANICS ON METAL-OXIDEELECTRODES, Electrochimica acta, 42(13-14), 1997, pp. 2009-2012
Citations number
12
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
42
Issue
13-14
Year of publication
1997
Pages
2009 - 2012
Database
ISI
SICI code
0013-4686(1997)42:13-14<2009:TFTAOO>2.0.ZU;2-Q
Abstract
A theoretical model describing the electrochemical oxidation of organi cs at oxide electrodes (MOx) forming the higher oxide (MOx+1) is descr ibed. In this model both organics oxidation and O-2 evolution are medi ated by the higher oxide (MOx+1) which is electrogenerated at the anod e surface. The effect of concentration polarization in the electrolyte is also included in the theoretical model. (C) 1997 Elsevier Science Ltd.