Gas-phase fluorination of fluorochloromethanes by CF3OF in the presence ofoxygen

Authors
Barkalov, IM Karnaukh, AA
Citation
Im. Barkalov et Aa. Karnaukh, Gas-phase fluorination of fluorochloromethanes by CF3OF in the presence ofoxygen, J FLUORINE, 96(1), 1999, pp. 71-75
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
96
Issue
1
Year of publication
1999
Pages
71 - 75
Database
ISI
SICI code
0022-1139(19990624)96:1<71:GFOFBC>2.0.ZU;2-O
Abstract
Systematic IR-spectroscopic and thermographic studies of product formation and kinetics of gas-phase branched chain fluorination of halomethanes (RH) by trifluoromethylhypofluorite (CF3OF) are reviewed. A model of the complic ated influence of both the oxygen and the intermediate olefins in the proce ss during the fluorination delays could possibly be extended to other gas-p hase fluorination systems with similar chain branching. (C) 1999 Elsevier S cience S.A. All rights reserved.