Reactions of pentafluorobenzoylpyruvic ester and its copper(II) chelate with dinucleophiles

Authors
Saloutin, VI Perevalov, SG
Citation
Vi. Saloutin et Sg. Perevalov, Reactions of pentafluorobenzoylpyruvic ester and its copper(II) chelate with dinucleophiles, J FLUORINE, 96(1), 1999, pp. 87-93
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
96
Issue
1
Year of publication
1999
Pages
87 - 93
Database
ISI
SICI code
0022-1139(19990624)96:1<87:ROPEAI>2.0.ZU;2-#
Abstract
Pentafluorobenzoylpyruvic ester reacts with dinucleophiles - hydrazine, phe nylhydrazine, hydroxylamine hydrochloride, 1,2-ethylenediamine, 1,2-phenyle nediamine, 2-aminophenol - to form heterocyclic compounds. Reactions betwee n bis(ethyl pentafluorobenzoylpyruvate)copper (II) chelate and these amine hydrochlorides also produce heterocycles. The analytical data of these comp ounds - elemental analysis, IR-, H-1 and F-19 NMR spectral data - are repor ted. (C) 1999 Elsevier Science S.A. All rights reserved.