Infrared spectroscopic studies of the Hofmann-daon-type clathrates: M(1,8-diaminooctane)Ni(CN)(4)center dot G (M = Co, Ni or Cd; G = 1,2-dichlorobenzene or 1,4-dichlorobenzene)

Authors
Sertbakan, TR Saglam, S Kasap, E Kantarci, Z
Citation
Tr. Sertbakan et al., Infrared spectroscopic studies of the Hofmann-daon-type clathrates: M(1,8-diaminooctane)Ni(CN)(4)center dot G (M = Co, Ni or Cd; G = 1,2-dichlorobenzene or 1,4-dichlorobenzene), J MOL STRUC, 483, 1999, pp. 75-79
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
483
Year of publication
1999
Pages
75 - 79
Database
ISI
SICI code
0022-2860(19990525)483:<75:ISSOTH>2.0.ZU;2-T
Abstract
New Hofmann-daon-type clathrates of the form M(1,8-diaminooctane)Ni(CN)(4). G (M = Co, Ni or Cd; G = 1,2-dichlorobenzene or 1,4-dichlorobenzene) were prepared in powder form and their infrared spectra are reported. The spectr al features suggest that these compounds are similar in structure to the en -Hofmann-type clathrates and their structure consists of corrugated polymer ic layers of {M-Ni(CN)(4)}(infinity) with the 1,8-diaminooctane spaned betw een two metal (M) atoms, of the consecutive two layers. (C) 1999 Elsevier S cience B.V. All rights reserved.