Structural information on transition metal(II) complexes of 4,4 '-bipyridyl and 4-phenylpyridine from their infrared spectra

Authors
Bayari, S Topacli, A Salih, B
Citation
S. Bayari et al., Structural information on transition metal(II) complexes of 4,4 '-bipyridyl and 4-phenylpyridine from their infrared spectra, J MOL STRUC, 483, 1999, pp. 165-169
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
483
Year of publication
1999
Pages
165 - 169
Database
ISI
SICI code
0022-2860(19990525)483:<165:SIOTMC>2.0.ZU;2-U
Abstract
The infrared spectra (4000-300 cm(-1)) are reported for metal(II) chloro 4, 4'-bipyridyl and 4-phenylpyridine complexes and metal(II)-isothiocyanate 4- phenylpyridine complexes of the following stoichiometries: [M(bipy)Cl-2] {M = Mn, Fe, Co or Ni}, [M(4-phpy)(2)Cl-2] {M = Fe, Co, Cd, Zn, Cu, Hg or Pd} and [M(4-phpy)(n)(NCS)(2)] {n = 2, M = Co, Ni, Zn or Cu; n = 4, M = Fe or Ni} and an assignment is proposed for all the infrared bands. (C) 1999 Else vier Science B.V. All rights reserved.