Synthesis and properties of tetrakis(trimethylsilyl)phthalocyaninatoruthenium(II)

Authors
Durr, K Hanack, M
Citation
K. Durr et M. Hanack, Synthesis and properties of tetrakis(trimethylsilyl)phthalocyaninatoruthenium(II), J PORPHYR P, 3(3), 1999, pp. 224-229
Citations number
22
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
ISSN journal
10884246 → ACNP
Volume
3
Issue
3
Year of publication
1999
Pages
224 - 229
Database
ISI
SICI code
1088-4246(199903)3:3<224:SAPOT>2.0.ZU;2-A
Abstract
Tetrakis(trimethysilyl)phthalocyaninatoruthenium(II) (5) has been synthesiz ed via the biaxially coordinated ((CH3)(3)Si)(4)PcRu(3-Clpy)(2) (2) complex by thermal decomposition of the axial Ligands of 2. ((CH3)(3)Si)(4)PcRu (5 ) was characterized by NMR, IR and UV-vis spectroscopy and elemental analys is. The trisubstituted ((CH3)(3)Si)(3)PcRu(3-Clpy)(2) (3) and disubstituted ((CH3)(3)Si)(2)PcRu(3-Clpy)(2) (4) complexes, formed as side products duri ng the thermolysis of 2, could be isolated and characterized. Copyright (C) 1999 John Wiley & Sons, Ltd.