Hw. Kim et al., Effect of oxidation on the room-temperature flexural strength of reaction-bonded silicon carbides, J AM CERAM, 82(6), 1999, pp. 1601-1604
The oxidation behavior of reaction-bonded silicon carbide (RBSC) and the ef
fect of oxidation on the room-temperature flexural strength of RBSC were in
vestigated. Four different types of RBSC, each having various SiC particle-
size distributions and free silicon contents, were exposed to air at 1300 d
egrees C for up to 200 h, Parabolic weight gains, with respect to oxidation
time, were observed in all the specimens, The strength of the RBSC increas
ed after oxidation for up to 50 h, because of the blunting of cracks by the
silica layer that was formed on the surface. However, with further oxidati
on, the beneficial role of the oxide layer was negated by the cracks that w
ere newly generated on the surface because of the thermal mismatch between
the substrate and the silica layer. The amount of free silicon had a neglig
ible effect on the strength retention of the specimens after the oxidation
processes.