N. Bowden et al., Mesoscale self-assembly of hexagonal plates using lateral capillary forces: Synthesis using the "capillary bond", J AM CHEM S, 121(23), 1999, pp. 5373-5391
This paper examines self-assembly in a quasi-two-dimensional, mesoscale sys
tem. The system studied here involves hexagonal plates ("hexagons") of poly
(dimethylsiloxane) (PDMS; 5.4 mm in diameter, 0.9-2.0 mm thick), with faces
functionalized to be hydrophilic or hydrophobic, floating at the interface
between perfluorodecalin (PFD) and H2O. The hexagons assemble by capillary
forces originating in the interactions of the menisci at their hydrophobic
and hydrophilic rectangular faces. The strength and directionality of the
interactions can be tailored by manipulating the heights of the faces, the
pattern of the hydrophobic faces, the pattern of hydrophobic regions on the
se faces, and the densities of the three interacting phases (organic Liquid
, aqueous liquid, polymeric solid). Examination of all 14 possible combinat
ions of hydrophobic and hydrophilic faces on the hexagonal plates led to th
ree outcomes: (i) the extension of the strategies of self-assembly from the
molecular to the mesoscale, (ii) the demonstration of a system in which sm
all objects can be designed to self-assemble into a variety of arrays, and
(iii) the hypothesis that capillary forces between objects can, in some cir
cumstances, be considered to form the basis for a "bond" between them-the c
apillary bond-and be used in synthesis in a way analogous to that in which
noncovalent bonds are employed in molecular-scale synthesis.