Determination of iodine value of palm oil by Fourier transform infrared spectroscopy

A rapid method for the quantitative determination of iodine value (IV) of p alm oil products by FTIR transmission spectroscopy is described. A calibrat ion standard was developed by blending palm stearin and superolein in speci fic ratios that covered a range of 27.9 to 65.3 IV units. The spectra of th ese standards was measured in the range between 3050 and 2984 cm(-1), corre sponding to the absorption band of =C-H cis stretching vibration. A partial least squares calibration model for the prediction of IV was developed to quantify the IV of palm oil products. A validation approach was used to opt imize the calibration with a correlation coefficient of R-2 = 0.9995 and a standard error of prediction of 0.151. This study concludes that the FTIR t ransmission approach can be used to determine the IV of palm oil products w ith a total analysis time per sample of less than 2 min for liquid samples.