When optimizing a 0.1 mu m gate etching process using a standard chemistry
and plasma operating conditions, we have observed an unsuspected behavior o
f thin gate oxides. By combining X-ray Photoelectron Spectroscopy (XPS) and
spectroscopic ellipsometry, we have attributed this behavior to reactive s
pecies penetration through the thin gate oxides. This phenomenon could play
an important role in the sub-0.1 mu m CMOS process optimization.