Sorption of chloride-ion, sulfate-ion and phosphate-ion in calcium silicate hydrates

Citation
A. Nakamura et al., Sorption of chloride-ion, sulfate-ion and phosphate-ion in calcium silicate hydrates, NIP KAG KAI, (6), 1999, pp. 415-420
Citations number
3
Categorie Soggetti
Chemistry
Journal title
NIPPON KAGAKU KAISHI
ISSN journal
03694577 → ACNP
Issue
6
Year of publication
1999
Pages
415 - 420
Database
ISI
SICI code
0369-4577(199906):6<415:SOCSAP>2.0.ZU;2-4
Abstract
This study discusses the capacity of sorption of various ions in calcium si licate hydrates. Chloride-ion, sulfate-ion and phosphate-ion were sorbed in synthesized calcium silicate hydrates (C-S-H). The amount of sorbed chlori de-ion, sulfate-ion and phosphate-ion in C-S-H were 172 mg/g, 54 mg/g and 6 67 mg/g, respectively, In the case of sorption of phosphate-ion, phosphate- ion and C-S-H reacted to produce hydroxyapatite. In the leaching test, 15% of chloride-ion, 18% of sulfate-ion and 34% of phosphate-ion were dissolved from C-S-H sorbing respective anions. On the other hand, 65% of fixed chlo ride-ion in Friedel's salt was dissolved in the leaching test. Therefore, t he fixing ability of chloride-ion in C-S-H is higher than that. in Friedel' s salt.