Waveforms of electron pairs in superconductors are investigated on the basi
s of the atomic nature. According to the orbital function and a potential e
nergy level for inner paired electrons in Thomas-Fermi-Dirac field, superco
nducting pairing states are determined by atomic number and radius. The s-
and d-wave pairings dominate for superconducting atoms with atomic numbers
(Z) less and more than 29, respectively. However, for exotic superconductor
s with crystal anisotropy and elemental superconductors of lacking crystal
rigidity, when one wavefunction of multicomponent pair states crosses nodal
surfaces of the orbital, the sign of the wavefunction changes, resulting i
n the appearance of p- and s-wave pairings for atoms with Z between 11 and
28, and more than 29, respectively.