Study of homogeneous hydrogenation of acetylene compounds with para-hydrogen and Pd(0) and Pt(0) complexes by in situ NMR spectroscopy

Authors
Sulman, E Deibele, C Bargon, J
Citation
E. Sulman et al., Study of homogeneous hydrogenation of acetylene compounds with para-hydrogen and Pd(0) and Pt(0) complexes by in situ NMR spectroscopy, REACT KIN C, 67(1), 1999, pp. 117-122
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
67
Issue
1
Year of publication
1999
Pages
117 - 122
Database
ISI
SICI code
0133-1736(199905)67:1<117:SOHHOA>2.0.ZU;2-K
Abstract
eta(2) -C60Pd(PPh3)(2), eta(2) -C60Pt(PPh3)(2) and C2H4Pt(PPh3)(2) have bee n used as catalysts for homogeneous hydrogenation of acetylene compounds en riched in pam-hydrogen (p-H-2). The study of the processes has been carried out by in situ NMR spectroscopy. It has been concluded that the nature of the substrate affects the intensity and patterns of polarization signals.