Some kinetic aspects regarding the preparation of 1-(2-methoxyethoxy)cyclododeca-2,6,10-triene

Authors
Balbolov, E Mitkova, M
Citation
E. Balbolov et M. Mitkova, Some kinetic aspects regarding the preparation of 1-(2-methoxyethoxy)cyclododeca-2,6,10-triene, REACT KIN C, 67(1), 1999, pp. 191-196
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
67
Issue
1
Year of publication
1999
Pages
191 - 196
Database
ISI
SICI code
0133-1736(199905)67:1<191:SKARTP>2.0.ZU;2-F
Abstract
The reaction of (E,E,E)-2,6,10-cyclododecatrien-1-yl acetate with 2-methoxy ethanol catalyzed by Pd-0(PPh3)(4) was studied in tetrahydropyran solutions at 358K. The selectivity of the unsaturated ether at conversion of allyl a cetate up to 68.1% ranged within 92.1-98.5%. The product composition was re lated to kinetic equations which can be used for reactor design.