Multiplicity of regimes in a dual-reactor system for partial oxidation of hydrocarbons with the catalyst unsteady state

Citation
Ea. Ivanov et Si. Reshetnikov, Multiplicity of regimes in a dual-reactor system for partial oxidation of hydrocarbons with the catalyst unsteady state, REACT KIN C, 67(1), 1999, pp. 213-218
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
67
Issue
1
Year of publication
1999
Pages
213 - 218
Database
ISI
SICI code
0133-1736(199905)67:1<213:MORIAD>2.0.ZU;2-L
Abstract
A mathematical modeling of a dual-reactor system based on a simple kinetic scheme with two types of sites (accounting for deep and partial oxidation) has been performed. It has been shown that it is possible to regulate the s tate of a catalyst in the reaction zone by varying the rate of the catalyst circulation between the reactors, thus, significantly increasing the react ion selectivity. A region of multiplicity of the process stationary regimes has been found. This region appeared to become smaller with the increase o f the catalyst circulation rate.