Kinetic stability of the dysprosium(III) complex with tetraazaporphine in water-acetic acid and methanol-acetic acid mixtures

Authors
Khelevina, OG Voinov, AA
Citation
Og. Khelevina et Aa. Voinov, Kinetic stability of the dysprosium(III) complex with tetraazaporphine in water-acetic acid and methanol-acetic acid mixtures, RUSS J C CH, 25(6), 1999, pp. 445-449
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
25
Issue
6
Year of publication
1999
Pages
445 - 449
Database
ISI
SICI code
1070-3284(199906)25:6<445:KSOTDC>2.0.ZU;2-4
Abstract
Water-soluble dysprosium tetraazaporphine complex with the acetylacetonate ion as an extra ligand was synthesized for the first time. Its kinetic stab ility in acetic acid solutions was studied. The complex was shown to underg o solvoprotolytic dissociation to form free tetraazaporphine. The kinetic p arameters for dissociation reaction are determined and the mechanism of rea ction is discussed.