Ca1-xPrxF2+x thin films, x varying from 0.01 to 0.10, were grown on Si (100
) substrates by sublimation under ultra-high vacuum of solid solution powde
rs obtained from high purity CaF2 and PrF3 initial powders. First, the synt
hesis of the bulk solid solutions was controlled using X-ray diffraction an
d Raman spectroscopy. A complete transformation seems to be obtained by hea
ting for 8 hours under vacuum the mixed initial powders at a temperature of
1400 K. However, for x 0.10, a Rutherford backscattering (RBS) of alpha pa
rticles study shows that to obtain homogeneous thin films a pre-evaporation
of the product at 1500 K during approximately 30 min is necessary. After s
uch a treatment, the films are of the desired composition and the Pr3+ ions
are uniformly distributed within the layers. On the other hand, for the lo
wer praseodymium contents, the alloy produced by heating the initial powder
s at 1400 K sublimes congruently. Moreover, in this case a RES study in cha
nneling conditions shows that the films are of epitaxial quality and a phot
oluminescence study shows that the interstitial fluoride ions, which balanc
e the rare earth trivalent ions in the matrix, are preferentially located i
n nn (nearest neighbor) sites, of C-4v symmetry (tetragonal). (C) 1999 Else
vier Science S.A. All rights reserved.