A quantum scattering theoretical study on the compound-state formation andthe rotational-state distribution of the product for the three-dimensionalstate-to-state H+H-2(v,j)-> H-2(v ',j ')+H reaction

Citation
Wc. Lu et al., A quantum scattering theoretical study on the compound-state formation andthe rotational-state distribution of the product for the three-dimensionalstate-to-state H+H-2(v,j)-> H-2(v ',j ')+H reaction, ACT CHIM S, 57(6), 1999, pp. 553-556
Citations number
12
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
57
Issue
6
Year of publication
1999
Pages
553 - 556
Database
ISI
SICI code
0567-7351(1999)57:6<553:AQSTSO>2.0.ZU;2-9
Abstract
This paper reports the three - dimensional state - to - state reaction prob abilities for the H + H-2 (nu,j)-->H-2(nu',j') + H system calculated by LCA C-SW (linear combination of arrangement channels-scattering wavefunction) a pproach. The compound-state formation (or energy resonance structure) of th is system is analyzed. The results of the rotational-state distribution for the product of this reaction show that the energy resonance is due to the interference effect between the translational motion of the system and the internal state of the reactant.