Characterization of thermal products of pure and mixed basic copper carbonate and aluminum hydroxide

Citation
Wm. Shaheen et Mm. Selim, Characterization of thermal products of pure and mixed basic copper carbonate and aluminum hydroxide, AFINIDAD, 56(480), 1999, pp. 129-134
Citations number
18
Categorie Soggetti
Chemistry
Journal title
AFINIDAD
ISSN journal
00019704 → ACNP
Volume
56
Issue
480
Year of publication
1999
Pages
129 - 134
Database
ISI
SICI code
0001-9704(199903/04)56:480<129:COTPOP>2.0.ZU;2-H
Abstract
A series of pure and mixed oxides [CuO-Al2O3] system were prepared by therm al treatment of pure and mixed basic copper carbonate and aluminum hydroxid e in temperature range 250 degrees-1000 degrees C. The thermal behavior of the pure and binary salts has been studied using thermal analysis (DTA & TG ) techniques. The thermal products were characterized by the x-ray diffract ion analysis. The results revealed that, basic copper carbonate and aluminu m hydro ride decompose at about 230 degrees and 225 degrees C respectively, to produce copper and aluminum oxides. A solid state reaction takes place between the thermal products and form copper aluminate compound. The combin ation of two oxides led to a noticeable change in the physical and chemical properties which in turn affects the catalytic properties. The catalytic a ctivity of the pure and mixed oxides produced at different temperatures wer e measured using the decomposition of hydrogen peroxide as a model reaction .