We report on prompt emission of fast electrons occurring during xenon-fluor
ide (351 nm) laser ablation of aluminum targets in the nanosecond regime. W
e have measured both the kinetic energy distribution and the energy-integra
ted time-of-flight distribution of these electrons. Experimental data evide
nce that the energetic electrons are produced during the laser pulse as a c
onsequence of two-photon processes, and that space-charge effects influence
the photoemitted electron kinetic energy, leading to prompt electrons kine
tic energy distributions extending up to approximate to 15 eV. (C) 1999 Ame
rican Institute of Physics. [S0003-6951(99)02927-7].