THE DETERMINATION OF FERROCENE AND ITS DERIVATIVES BY QUENCHING OF FLUORESCENCE

Citation
Zk. Si et al., THE DETERMINATION OF FERROCENE AND ITS DERIVATIVES BY QUENCHING OF FLUORESCENCE, Analytical letters, 30(7), 1997, pp. 1407-1414
Citations number
9
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032719
Volume
30
Issue
7
Year of publication
1997
Pages
1407 - 1414
Database
ISI
SICI code
0003-2719(1997)30:7<1407:TDOFAI>2.0.ZU;2-K
Abstract
A method is described for the determination of ferrocene and its deriv atives by the fluorescence quenching of m-2-benzoyl-indan-1,3-dionecet yltrimethyl-ammonium bromide(CTMAB) system. Under the optimum conditio ns, the decrease of the fluorescence intensity was a linear function o f the concentration of ferrocene or its derivatives in the range 1.0x1 0(-6)-1.0x10(-5) mol/L. The detection limit was 1.0x10(-7) mol/L. The system was used for the determination of ferrocene n-heptyl beta-diket one, with satisfactory results.