Kinetics of the formation of metal-containing polymer composite

Citation
Nd. Zhuravlev et al., Kinetics of the formation of metal-containing polymer composite, COLL J, 61(3), 1999, pp. 292-295
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
COLLOID JOURNAL
ISSN journal
1061933X → ACNP
Volume
61
Issue
3
Year of publication
1999
Pages
292 - 295
Database
ISI
SICI code
1061-933X(199905/06)61:3<292:KOTFOM>2.0.ZU;2-R
Abstract
Numerical simulation of the formation kinetics of the metallic phase in a p olymer system due to thermal decomposition of metal-containing reagents was performed. It was assumed that the nuclei of the new phase are formed due to homogeneous nucleation and their growth is governed by the diffusion pro cesses. It was shown that the model qualitatively reproduces the available experimental data. The effect of the regime of addition of a decomposing re agent on the particle sizes was analyzed. It was disclosed that polymodal p article size distributions may be formed in a systems under certain specifi c regimes.