Numerical simulation of the formation kinetics of the metallic phase in a p
olymer system due to thermal decomposition of metal-containing reagents was
performed. It was assumed that the nuclei of the new phase are formed due
to homogeneous nucleation and their growth is governed by the diffusion pro
cesses. It was shown that the model qualitatively reproduces the available
experimental data. The effect of the regime of addition of a decomposing re
agent on the particle sizes was analyzed. It was disclosed that polymodal p
article size distributions may be formed in a systems under certain specifi
c regimes.