Sv. Kotomin et Nn. Avdeev, Wetting of synthetic fibers by thermoplastic melts during capillary impregnation of filaments, COLL J, 61(3), 1999, pp. 306-313
A method for the determination of the rates of impregnation and wetting dur
ing capillary impregnation (with a number of thermoplastics) of chemical fi
ber bundles (filaments) used for the reinforcement of polymer composites wa
s developed. The rate of wetting was proposed as the most objective charact
eristic of wetting of a fiber surface under dynamic conditions of impregnat
ion with a viscous polymer melt. Based on experimental data, the values of
the capillary pressure and the parameters of wetting of carbon and heat-res
istant synthetic fibers by melts of polyolefins, polyamides, and polyesters
were calculated. The kinetic character of wetting and the formation of adh
esive contact between the fiber surface and the thermoplastic melt is confi
rmed by the pattern of changes in rigidity during filament torsion in the i
mpregnation process.