Muon spin relaxation measurements in transverse and zero magnetic fiel
ds reveal muonium atom formation to be a thermally activated process i
n Al2O3 (sapphire) crystal. Experiments in electric fields up to 100 k
V/cm unambiguously show that muonium is formed via the delayed channel
of the radiolysis electron (created in the muon's track) transport to
the mu(+). The formation of the ''electronic polaron'' is believed to
be the limiting mechanism for electron transport in sapphire.